Printing Platinum and Palladium with Rives BFK
This has become one of my favorite papers lately. It is a print makers paper, which means that it has more internal sizing than external sizing, and tends to be pretty absorbent as compared to a paper such as COT320, Platine or Platinotype. But the hot-pressed version of this paper has a wonderful texture - soft without being ‘bumpy’ - and a seeming ability to create very rich, deep and velvety blacks, with only a single coating of sensitizer and metal. The paper is readily available in several weights at most art supply stores across the country. Once it is treated, it is also dimensionally stable, making it an excellent choice for multiple printing techniques such as gum-over-platinum. It is also inexpensive. In other words, it has a lot going for it. But like all papers, it has its own quirky requirements for making rich prints. So here is my working method for making it sing.
Buy the paper
First, you must buy the right paper. I would recommend buying either the 280gsm or the 175gsm Rives BFK hot press in white as a starting point. One of the maddening things about Rives BFK is that it seems to have as many versions as there are stars in the evening sky. But the two just mentioned are excellent choices.
Treat the paper
The paper as it comes is buffered and thus inimical to the acidic platinum and palladium chemistry. So the first task is to soak the paper for five minutes in a warm bath of 1-2% oxalic acid. I make this bath by adding 30g of oxalic acid to 2 liters of 110 degree water and pouring it in a large tray. I put the paper one sheet at a time in the tray and submerge it completely. You will see tiny little bubbles form on the surface. These bubbles are evidence of the buffering agents being neutralized and releasing carbon dioxide gas. This is not an environmental problem at all. One small bowl of salsa and some Cuban black beans will likely stimulate more carbon dioxide release than neutralizing 20 sheets of Rives.Wow. Why did I write that?Anyway.Keep adding paper until the top sheet won’t stay submerged. Keep an eye on the clock, and after 5 minutes are up, take the first sheet off of the bottom and hang it up to dry. Do this with the other sheets after they have all been soaking for five minutes. As you might guess, this is not the most intellectually stimulating task that you will undertake in the darkroom, so it is an excellent idea to do as many sheets at one time as your drying area can handle. Then store the sheets for quick and easy printing over the following weeks.
Coat the paper
Once the paper is dry, you can coat and print. But Rives has some peculiar properties that call for some slight tweaks in normal platinum-palladium printing practices.The first deviation is in the coating and drying of the senstizer and metal. It is very absorbent paper, which means that it acts like a sponge in absorbing the costly ferric oxalate and metal compounds. The first modification is in ‘extending’ the sensitizer volume slightly with distilled water. I extend it about 25%. What this means is that if my total drop count is 10 drops of ferric oxalate and 10 drops of palladium, I will add an additional 5 drops of distilled water to give me more solution volume. This buys me additional time to use the magic brush to ‘work’ the solution into the paper in an even coating. (As an aside, the magic brush refers to the Richeson 9010 brush, the best brush for alt process work that I have yet found. Buy one and life will be good. We will try to publish a short article on the brush later on.)
Dry the paper
Now, allow the coating to dry for one minute. Yes, that is sixty seconds. Then dry it with a hairdryer set to medium heat, working the airflow back and forth in an even pattern until the coating is dry.
Rehumidify the paper
The next tweak to the process involves waiting. What is needed to get a nice rich print with a lot of Dmax is humidity in the paper while it is being exposed. And you have just driven all the humidity from the paper with the blow dryer. So put the paper in a dark place and let it rehumidify for 15-20 minutes or so. My darkroom is climate controlled, and I try to maintain about a 40-50% relative humidity as an ambient level. This amount of humidity is sufficient to yield a nice rich print. If you live in an arid area, an investment in a humidification box would be worthwhile to enable you to rehumidify the paper to somewhere between 40 and 60%.(As an aside, I always wondered why my prints were always warmer toned when I printed them in the winter versus the summer. I finally realized that it was the change in the ambient humidity. In the winter, my darkroom will sometimes be in the 30% range versus 45-50% in the summer. This difference in humidity will affect both the print color and the contrast to some extent. Being able to control your humidity is an excellent way to add some additional controls to your printing bag of tricks.)
Expose the print
Moving on, your print has now been coated, dried and rehumidified. So now it is time to expose it. If your print requires a long exposure and you are using a vacuum frame, a piece of mylar should be put between the vacuum blanket and the back of the print. There is nothing like a vacuum to suck all the moisture out of a print, and the mylar will allow you to maintain the desired humidity level in the print.
Develop the print
I use potassium oxalate developer at 120 to 140 degrees to develop my straight platinum/palladium prints. If I intend to use it for a gumover print, I will use the developer at 105 degrees. In general, the warmer the developer, the warmer tone your final print will have. A warmer developer will also increase the printing speed and lower the contrast, which is an oblique way of saying that you should make your test strips using the same developer temperature you intend to use for your final print. Now here is the first tweak from what some people regard as normal practice: Leave the print in the developer and agitate gently for five minutes. I know that it looks like it develops instantly and that the developer could immediately be poured back into its container, but the additional soak in the developer will enhance the subsequent clearing of the print.
Clear the print
BFK is a very absorbent paper. Which means that it does not let go of the unused ferric oxalate sensitizer without a fight. So do not make your life difficult by soaking the print in plain water at this point. Splurge on a ten pound canister of citric acid from http://www.chemistrystore.com , and soak the print for five minutes in a tray filled with 2 heaping tablespoons of citric acid per liter of water.Next, gently agitate the print for five minutes in each of two subsequent trays containing a solution of Kodak Hypoclear (or its homemade equivalent) diluted 1:3 (instead of the standard 1:4 dilution) with 1 tablespoon of EDTA tetrasodium per liter added as an additional aid to clearing. When tray number two starts looking lemonade yellow, dump it and move tray number three into its place and mix up a fresh batch of hypoclear/EDTA for the new tray number three.Just as it is important to clear adequately, it is also important to not clear too much, since the print can begin bleaching and losing density if it is allowed to languish in a bath of hypoclear too long. In other words, use the timer, and keep an eye on the total amount of time the print spends in the clearing bath.
Wash the print
Unlike their silver gelatin cousins, platinum prints do not need extensive washing to become stable. Once the unused ferric oxalate has been removed by the clearing baths, the only goal of washing the print is to remove the chemical residue of the clearing baths. I generally wash the prints for twenty minutes and then hang them to dry.
Summary
I want to point out that Rives BFK represents an interesting case when it comes to platinum printing. When I approached this paper using the same procedural methods I had been using for COT320 (for instance) my prints were underwhelming. But slight modifications and adjustments of the procedures to account for the absorbent nature of this paper have given me a fantastic, inexpensive option for platinum printing. That is not a bad thing, in my opinion. –Clay Harmon